An evaluation of Acacia mearnsii tannin as an aluminum corrosion inhibitor in acid,alkaline, and neutral media

The electrochemical behavior of aluminum in tannin from Acacia mearnsii bark was evaluated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) in media under three different pH conditions: acid, alkaline, and neutral. A relationship among pH, polymerization grade (PG), zeta potential, surface, and electrochemical properties was observed in the inhibition performance of the tannin. At high pH, the oligomer structure of the tannin was affected, resulting in a low PG (4) and high zeta potential (−75 mV), and consequently, the inhibition efficiency decreased (68%) in comparison with that in acid (99%) and neutral media (96%). The values obtained indicate a physisorption mechanism for the aluminum corrosion inhibition in the studied conditions.     

Effect of microstructure on discharge performance of Al–0.8Sn–0.05Ga–0.9Mg–1.0Zn (wt%) alloy as anode for seawater-activated battery

The electrochemical performance and discharge behavior of Al–0.8Sn–0.05Ga–0.9Mg–1.0Zn (wt%) alloys in as-cast, homogenized, and annealed states were investigated through electrochemical means, corrosion rate test, and discharge test in a 3.5 wt% NaCl solution. Results suggest that the discharge performance of this alloy is enhanced by rolling and subsequent annealing treatment. This is attributed to the fact that the microstructure of the alloy is greatly improved through rolling and subsequent annealing treatment. The 400°C-annealed alloy exhibits the most excellent discharge activity than alloys in other states, which is due to more regions being activated by a finer and more uniform Sn-rich phase. Furthermore, the anode efficiency of the 400°C-annealed alloy is higher than that of as-cast and homogeneous alloys due to the more uniform distribution of Sn in the aluminum matrix.     

基于十字形阵列和2D-MUSIC算法的Lamb波检测

采用由压电传感器组成的十字形阵列进行Lamb波信号的激励和接收，提出一种二维多重信号分类（2D-MUSIC）方法对铝板中的缺陷进行定位检测。选用合适的频率激励产生单一模态信号，可避免多模态的影响，降低Lamb波的频散；利用2D-MUSIC算法对接收信号进行分段处理，并结合反射信号和二维导向矢量对铝板中的缺陷进行定位。结果表明，提出的2D-MUSIC算法对铝板中的缺陷定位比传统MUSIC算法更精准。     

拉锻式摩擦塞焊的热力耦合解析模型和试验验证

为快速得到拉锻式摩擦塞焊的焊接工艺参数，对焊接过程进行预测，建立了摩擦塞焊过程的扭矩、轴向力、功率和能量等指标的力学模型和热力耦合解析模型。模型的输入量为焊接塞棒的几何参数、材料属性、焊接转速和进给速度，输出量为焊接过程的扭矩、轴向力、功率和能量等。在自主设计的拉锻式摩擦塞焊设备上进行了焊接试验。通过将试验数据的输入和输出指标与理论模型值进行对比分析，验证了理论解析模型的可行性。     

Preparation of Pt/Ce–Zr–Y mixed oxide/anodized aluminium oxide catalysts for hydrogen passive autocatalytic recombination

The use of a Pt-based catalyst was evaluated for autocatalytic hydrogen recombination. The Pt was supported on a mixture of Ce-, Zr- and Y-oxides (CZY) to yield nanosized Pt particles. The Pt/CZY/AAO catalyst was then prepared by the spray-deposition of the Pt/CZY intermediate onto an anodized aluminium oxide (AAO) layer on a metallic aluminum core. The Pt/CZY/AAO catalyst (3 × 1 cm) was evaluated for hydrogen combustion (1–8 vol% hydrogen in the air) in a recombiner section testing station. The thermal distribution throughout the catalyst surface was investigated using an infrared camera. The maximum temperature gradient (ΔT) for the examined hydrogen concentrations did not exceed 36 °C. The Pt/CZY/AAO catalyst was also evaluated for prolonged hydrogen combustion duration to assess its durability. An average combustion temperature of 239.0 ± 10.0 °C was maintained for 53 days of catalytic hydrogen combustion, suggesting that there was limited, or no, catalyst deactivation. Finally, a Pt/CZY/AAO catalytic plate (14.0 × 4.5 cm) was prepared to investigate the thermal distribution. An average surface temperature of 212.5 °C and a maximum ΔT of 5.4 °C was obtained throughout the catalyst surface at a 3 vol% hydrogen concentration.     

电熔剂法净化处理铝熔体的影响因素

基于正交试验,研究工业纯铝中去除氧化夹杂物的电熔剂处理技术的净化效果及其影响因素。结果表明,熔剂层厚度是影响净化效果的主要因素。最佳工艺参数:电流15A、精炼温度70 0℃、流股直径7mm、熔剂层厚度2 0～3 0mm。铝合金中夹杂物去除率可达84 4%,力学性能尤其是塑性得到了较大幅度的提高     

ZL201铝合金的触变锻造组织与性能

利用自行设计的模具,采用半固态触变锻造的方法,研究近液相线铸造法制备的ZL201铝合金半固态坯料触变成形件的组织和性能.结果表明,半固态闭模锻造成形后的成形件组织均匀、致密.合金在525℃～530℃固溶12h、155℃时效20h后,强化相充分溶解,均匀析出,合金的维氏硬度可达129.8HV.半固态触变锻造可以获得理想的成形件.     

5083和7020变形铝合金加工图的研究

在动态材料模型理论基础上,对5083和7020两种典型变形铝合金的加工图进行研究分析,结果表明:5083铝合金适宜加工区的温度为450～500℃、应变速率为0.005～0.1s-1;7020铝合金适宜加工区的温度为450～550℃、应变速率为0.001～O.1s-1.同时通过选取7020铝合金在不同加工条件下的压缩试样...     

ICP—AES法测定黄铜中的铅铁铋镍铝锑

用电感耦合等离子体发射光谱法可直接测定黄铜中的铅铁铋镍铝锑6种元素的含量．通过试验优化出各元素的分析波长和分析条件，且用基体匹配补偿基体效应．该法流程简单，分析快速，回收率为95％～105％，相对标准偏差小于2．5％。